adverb, noun
Rare literary word. Can refer to the continuous span of day and night, or specifically to the onset of evening. Modern Japanese normally uses 昼夜 for 'day and night' and 日暮れ or 夕暮れ for 'nightfall'.
日夕、彼はその仕事に打ち込んだ。
Day and night, he devoted himself to that work.
日夕の頃、山の端が赤く染まった。
Around nightfall, the mountain ridge was dyed red.