expression
Used to express surprise, disappointment, or irony that a particular person (often someone trusted or expected to behave better) did something. Typically followed by a negative or unexpected action.
人もあろうに、彼がそんな嘘をつくとは思わなかった。
Of all people, I never thought he would tell such a lie.
人もあろうに、先生が遅刻するなんて。
Of all people, the teacher being late!