noun
gap moe; attraction to a gap between appearance and true nature
Slang from otaku culture; describes finding someone endearing when their behavior or personality unexpectedly contrasts with their outward image (e.g., a tough-looking person being gentle).
普段はクールな先輩が子猫に優しく話しかけていて、ギャップ萌えした。
My usually cool senior was talking gently to a kitten, and I felt gap moe.
彼女のギャップ萌えポイントは、真面目な顔して実は甘党なところだ。
Her gap moe point is that she looks serious but actually has a sweet tooth.