Related words に当たり is a more formal, written-style variant of に当たって , both meaning 'on the occasion of' or 'when doing'.
際に is a more neutral, general-purpose equivalent usable in both casual and formal speech, while に当たって is reserved for formal or ceremonial contexts.
にあたって and にあたっては mean the same thing, but the は in にあたっては emphasizes the introduced matter as the topic or condition under discussion.
に際して and にあたって are nearly interchangeable formal expressions meaning 'on the occasion of,' though に際して leans slightly more toward emphasizing the timing of the event.
Don't confuse with に当たって marks the moment of undertaking an action ('when doing X'), while にあっては marks the surrounding situation or circumstance ('in such a situation'), so they aren't interchangeable despite both sounding formal.
Etymology Derived from the verb 当たる (to hit, to correspond) in its te-form, combined with the particle に . The expression literally means 'in hitting/corresponding to' and developed into a formal marker for occasions.
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