Usage patterns
〈時〉に二回twice per (day/week/etc.)
I go to a yoga class twice a week.
二回に分けて〈動詞〉to do something in two installments/parts
I made the payment in two installments.
〈事〉を二回繰り返すto repeat something twice
The teacher repeated the same explanation twice.
二回目の〈物・事〉the second (time doing something)
This is my second date with her.