the moment of meeting; the moment of running into each other; the moment of crossing paths
Refers to the instant when two people, vehicles, etc., encounter each other, often unexpectedly or head-on. Commonly used in the phrase 出会い頭に.
出会い頭に自転車とぶつかりそうになった。
I almost collided with a bicycle at the moment we met.
Please be careful of accidents that happen when crossing paths.