Usage patterns
各国の〈人〉each country's (representative/leader, etc.)
The prime ministers of each country attended the conference.
各国が〈動詞〉するeach country does (something), e.g. cooperates, responds
Each country is cooperating to tackle environmental issues.
各国と〈事〉するto do something (negotiate, trade, etc.) with each country
Japan has concluded trade agreements with various countries.
Expressions
各国間among countries; between countries; international